Question: Adapted from problems 2 . 1 8 and 2 . 1 9 ( 4 0 marks ) The attractive ( E A ) and repulsive
Adapted from problems and marks The attractive and repulsive
potential energies are described as such, where and are constants and is the interatomic radius:
c For a ion bond pair, we have and Plot
and identify and for this system for
d Based on the plot, estimate and
e The equilibrium bond length and equilibrium bond energy occur at the bond length which
Based on this knowledge, find an expression for and in terms of and
Hint: remember optimization problems; the optimum occurs when the derivative is Start by finding
f Based on e calculate and and compare to the graphical estimations from part d
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