Question: Adapted from problems 2 . 1 8 and 2 . 1 9 ( 4 0 marks ) The attractive ( E A ) and repulsive

Adapted from problems 2.18 and 2.19(40 marks) The attractive (EA) and repulsive (ER)
potential energies are described as such, where A,B, and n are constants and r is the inter-atomic radius:
EA=-Ar,ER=Brn
c. For a K+-Cl-ion bond pair, we have A=1.436eVnm,B=5.8610-6eVnm9, and n=9. Plot
and identify EA,ER, and EN for this system for 0.2nmr0.8nm
d. Based on the plot, estimate r0 and E0
e. The equilibrium bond length (r0) and equilibrium bond energy (E0) occur at the bond length which
minimizesEN. Based on this knowledge, find an expression for r0 and E0 in terms of A,B, and n.
Hint: remember optimization problems; the optimum occurs when the derivative is 0. Start by finding
dENdr
f. Based on (e), calculate r0 and E0, and compare to the graphical estimations from part (d).
Adapted from problems 2 . 1 8 and 2 . 1 9 ( 4 0

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