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V-200 R-200 Oxychlorination reador D-200 Decanter P-200 Reactor pump Evaporator Pyrolysis face Quendo Gas Oxygen 1 0-300 A-200 Chlorine Dirty water 10 4 12 9 E-200 200 -200 14 V-200 HHH 16 T-300 13 T-203 17 15 20 2081 VC 206 Recycle cooler E-205 VC column reboller - 204 VC column condenser T-30 VC column 30 HCI Column reboer 201 Quench Column HC column condenser Figure 1: EFD for oxychlorination process. 1.97. 10 Net du -1.1110 Hmong 10 2.500 GAAN er ar o 1,500 CH 2.500 HO 3.750 Owychlorination 260C, 10 Dec Temperature change dang 1 Temperature change 10310 10 SOOC Tampe change 8.33 30/ Temperature change 1:23 20'. CHO 5.250 Figure 2: PFD for oxychlorination process 9.9 99 3 o 14.500 750 Table OC.1 - Stream summaries for oxychlorination process. Stream Number 1 2 3 5 6 7 TemperatureTC) 2:50 250 250 120.9 260 -352 -35.2 -352 Pressure Atml 10 10 10 1 1 1 Vapor fraction 1 1 1 1 1 1 . 0 Massflow.hr 1,500 2.500 3,750 7,250 11.250 1.250 8.750 Molar flowtimol/hr) 44 89 104 196 194 13 8S 96 Componentholarlowmo/hr): Ethylene 0 885 0 0.7 33 26 0 07 Hydrogen chloride 0 0 103.7 194.9 163 8.6 0 7.7 Oxygen 443 0 0 0 13 13 0 12-dichloroethane 0 0 0 85.9 0 0 859 Water 0 0 0 86 0 84.6 14 Vinylchloride 0 . 0.8 08 0.1 0 08 Chlorine 0 0 0 0.1 0 0 0.1 1.1.2.trichloroethane 0 0 0 0 0 0 0 1,4-dichlorobutane 0 0 O O 0 0 0 Stream Number 10 11 12 13 14 15 16 17 Temperaturer) -0.2 242 500 6 2224 79.1 13.1 1114 Pressure Atm 26 26 26 12 12 12 48 48 Vapor fraction 0 1 1 0 1 0 0 Massflower 14.500 14.500 14.500 14.500 3.500 11.000 5.250 5.750 Molaroilmol/hr) 164 164 244 244 93 140 84 67 Componentelor low mol/hr) Ethylene 0.7 0.7 0.7 0.2 0.7 0 O Hydrogenitoride 7.7 7.7 91.2 91.2 91.2 0 0 0 Oxygen 0 0 0 0 0 0 . O 12-dichlorethane 138.7 138 53 53 0 53 01 528 Water 127 12.7 123 12) 0 113 1 113 Vinyloride 18 38 862 862 0.8 85.4 24 3 Chlorine 0.1 0.1 0.05 0.05 0 0.05 0.05 0 1.1.2 trichloroethane 0.05 0.05 0.05 0.05 0 0.05 0 0.05 1.4 dichorobutane 0.05 0.05 0.05 0.05 0 0.05 0 0.05 07 7.7 0 1387 12.7 3.8 01 0.05 0.05 18 335 48 5.750 67 0 0 528 11 0 0.05 0.05 Reactions in direct chlorination reactor are: C2H2 + 2 HCI+0.5 0: -(R11) CzHaCl2 + H20 CxHaCl2 + HCl + 0.5 02-(12) CHCI) Reactions in pyrolysis are: CzH4Cl - (R3) CzH,Cl + HCI CH3C1-(R4) CH2 + HCI CxHaCl2 -(R5) CH4 + Cl2 V-200 R-200 Oxychlorination reador D-200 Decanter P-200 Reactor pump Evaporator Pyrolysis face Quendo Gas Oxygen 1 0-300 A-200 Chlorine Dirty water 10 4 12 9 E-200 200 -200 14 V-200 HHH 16 T-300 13 T-203 17 15 20 2081 VC 206 Recycle cooler E-205 VC column reboller - 204 VC column condenser T-30 VC column 30 HCI Column reboer 201 Quench Column HC column condenser Figure 1: EFD for oxychlorination process. 1.97. 10 Net du -1.1110 Hmong 10 2.500 GAAN er ar o 1,500 CH 2.500 HO 3.750 Owychlorination 260C, 10 Dec Temperature change dang 1 Temperature change 10310 10 SOOC Tampe change 8.33 30/ Temperature change 1:23 20'. CHO 5.250 Figure 2: PFD for oxychlorination process 9.9 99 3 o 14.500 750 Table OC.1 - Stream summaries for oxychlorination process. Stream Number 1 2 3 5 6 7 TemperatureTC) 2:50 250 250 120.9 260 -352 -35.2 -352 Pressure Atml 10 10 10 1 1 1 Vapor fraction 1 1 1 1 1 1 . 0 Massflow.hr 1,500 2.500 3,750 7,250 11.250 1.250 8.750 Molar flowtimol/hr) 44 89 104 196 194 13 8S 96 Componentholarlowmo/hr): Ethylene 0 885 0 0.7 33 26 0 07 Hydrogen chloride 0 0 103.7 194.9 163 8.6 0 7.7 Oxygen 443 0 0 0 13 13 0 12-dichloroethane 0 0 0 85.9 0 0 859 Water 0 0 0 86 0 84.6 14 Vinylchloride 0 . 0.8 08 0.1 0 08 Chlorine 0 0 0 0.1 0 0 0.1 1.1.2.trichloroethane 0 0 0 0 0 0 0 1,4-dichlorobutane 0 0 O O 0 0 0 Stream Number 10 11 12 13 14 15 16 17 Temperaturer) -0.2 242 500 6 2224 79.1 13.1 1114 Pressure Atm 26 26 26 12 12 12 48 48 Vapor fraction 0 1 1 0 1 0 0 Massflower 14.500 14.500 14.500 14.500 3.500 11.000 5.250 5.750 Molaroilmol/hr) 164 164 244 244 93 140 84 67 Componentelor low mol/hr) Ethylene 0.7 0.7 0.7 0.2 0.7 0 O Hydrogenitoride 7.7 7.7 91.2 91.2 91.2 0 0 0 Oxygen 0 0 0 0 0 0 . O 12-dichlorethane 138.7 138 53 53 0 53 01 528 Water 127 12.7 123 12) 0 113 1 113 Vinyloride 18 38 862 862 0.8 85.4 24 3 Chlorine 0.1 0.1 0.05 0.05 0 0.05 0.05 0 1.1.2 trichloroethane 0.05 0.05 0.05 0.05 0 0.05 0 0.05 1.4 dichorobutane 0.05 0.05 0.05 0.05 0 0.05 0 0.05 07 7.7 0 1387 12.7 3.8 01 0.05 0.05 18 335 48 5.750 67 0 0 528 11 0 0.05 0.05 Reactions in direct chlorination reactor are: C2H2 + 2 HCI+0.5 0: -(R11) CzHaCl2 + H20 CxHaCl2 + HCl + 0.5 02-(12) CHCI) Reactions in pyrolysis are: CzH4Cl - (R3) CzH,Cl + HCI CH3C1-(R4) CH2 + HCI CxHaCl2 -(R5) CH4 + Cl2
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