P17F.9* J. Czarnowski and H.J. Schuhmacher (Chem. Phys. Lett. 17, 235 (1972)) suggested the following mechanism...

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P17F.9* J. Czarnowski and H.J. Schuhmacher (Chem. Phys. Lett. 17, 235 (1972)) suggested the following mechanism for the thermal decomposition of F,O in the reaction 2 F,O(g) → 2 F,(g) + 0,(g): (1) F,O+ F,O → F+ OF + F,O k, (2) F+F,0 → F, + OF (3) OF + OF →0,+ F+F (4) F+F+F,0 →F, + F,0 ke ka Use the steady-state approximation to show that this mechanism is consistent with the experimental rate law -d[F,O]/dt = k,[F,O]° + K[F,O]2. P17F.9* J. Czarnowski and H.J. Schuhmacher (Chem. Phys. Lett. 17, 235 (1972)) suggested the following mechanism for the thermal decomposition of F,O in the reaction 2 F,O(g) → 2 F,(g) + 0,(g): (1) F,O+ F,O → F+ OF + F,O k, (2) F+F,0 → F, + OF (3) OF + OF →0,+ F+F (4) F+F+F,0 →F, + F,0 ke ka Use the steady-state approximation to show that this mechanism is consistent with the experimental rate law -d[F,O]/dt = k,[F,O]° + K[F,O]2.