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Please estimate the gas phase and liquid phase fugacity coefficients, the Poynting Correction Factors, and the overall fugacity coefficients for acetone and methanol at 75 C and 100 atm. For purposes of the calculations, assume y = y2 = 0.5. C 8 C6H6 Table B.2: Constants for the Antoine Equation for Vapor Pressures of Pure Species B In p sat/kPa = A t/C+C Latent heat of vaporization at the normal boiling point (AHA), and normal boiling point (In). Parameters for Antoine En. Temp. Range , In Name Formula At B C kJ/mol C Acetone C3H60 14.3145 2756.22 228.060 -26 - 77 29.10 56.2 Acetic acid C2H4O2 15.0717 3580.80 224.650 24 - 142 23.70 117.9 C2H3N -27 14.8950 3413.10 250.523 81 Acetonitrile* 81.6 30.19 Benzene 13.7819 2726.81 217.572 6-104 30.72 80.0 iso-Butane CH10 13.8254 2181.79 248.870 -83-7 21.30 -11.9 n-Butane CH10 13.6608 2154.70 238.789 -73 - 19 22.44 -0.5 1-Butanol C4H100 15.3144 3212.43 182.739 37-138 43.29 117.6 2-Butanol C4H100 15.1989 3026.03 186.500 25-120 40.75 99.5 iso-Butanol C4H100 14.6047 2740.95 166.670 30 128 41.82 107.8 tert-Butanol C4H100 14.8445 2658.29 177.650 10 101 39.07 82.3 Carbon tetrachloride CCL 14.0572 2914.23 232.148 -14-101 29.82 76.6 Chlorobenzene CHCI 13.8635 3174.78 211.700 29 159 35.19 131.7 1-Chlorobutane C4H9C1 13.7965 2723.73 218.265 -1779 30.39 78.5 Chloroform CHCl3 13.7324 2548.74 218.552-23-84 29.24 61.1 Cyclohexane C6H12 13.6568 2723.44 220.618 9- 105 29.97 80.7 Cyclopentane CH10 13.9727 2653.90 234.510 -35-71 27.30 49.2 n-Decane CH22 13.9748 3442.76 193.858 65 - 203 38.75 174.1 Dichloromethane CH2C12 13.9891 2463.93 223.240 -38-60 28.06 39.7 Diethyl ether C4H100 14.0735 2511.29 231.200 -43-55 26.52 34.4 1,4-Dioxane C4H8O2 15.0967 3579.78 240.337 20-105 34.16 101.3 n-Eicosane C20H42 14.4575 4680.46 132.100 208 - 379 57.49 343.6 Ethanol C2H60 16.8958 3795.17 230.918 3-96 38.56 78.2 Ethylbenzene CgH10 13.9726 3259.93 212.300 33-163 35.57 136.2 Ethylene glycol C2H602 15.7567 4187.46 178.650 100_222 50.73 197.3 n-Heptane C7H16 13.8622 2910.26 216.432 4 123 31.77 98.4 n-Hexane C6H14 13.8193 2696.04 224.317 -19 92 28.85 68.7 Methanol CHO 16.5785 3638.27 239.500 -11 83 35.21 64.7 Methyl acetate C3H6O2 14.2456 2662.78 219.690 -23-78 30.32 56.9 Methyl ethyl ketone C4H30 14.1334 2838.24 218.690 -8 -103 31.30 79.6 Nitromethane CH3NO2 14.7513 3331.70 227.600 56 146 33.99 101.2 DO 150R CZ Table 13.10: Parameter Values for the Wilson and NRTL Equations Parameters (12, 021, 612, and b21 have units of calmol-', and V and V, have units of cm-mol-, V. Wilson Equation NRTL Equation System V2 012 021 b12 b21 Acetone(1) 74.05 291.27 1448.01 631.05 1197.41 0.5343 Water(2) 18.07 Methanol(1) 40.73 107.38 469.55 -253.88 845.21 0.2994 Water(2) 18.07 1-Propanol(1) 75.14 775.48 1351.90 500.40 1636.57 0.5081 Water(2) 18.07 Water(1) 18.07 1696.98 -219.39 715.96 548.90 0.2920 1,4-Dioxane(2) 85.71 Methanol(1) 40.73 504.31 196.75 343.70 314.59 0.2981 Acetonitrile(2) 66.30 Acetone(1) 74.05-161.88 583.11 184.70 222.64 0.3084 Methanol(2) 40.73 Methyl acetate(1) 79.84 -31.19 813.18 381.46 346.54 0.2965 Methanol(2) 40.73 Methanol(1) 40.73 1734.4 183.04 . 730.09 1175.41 0.4743 Benzene(2) 89.41 Ethanol(1) 58.68 1556.45 210.52 713.57 1147.86 0.5292 Toluene(2) 106.85 Values are those recommended by Gmehling et al. Vapor-Liquid Equilibrium Daru Collection. Chemistry Data Series, vol. I, parts la, lb, 2c, and 24. DECHEMA. Frankfurt Main. 1981-1988