Switch Sn Voltmeter Salt Bridge Wire Metal X 1.0 M Sn(NO) 1.0 M X(NO), An electrochemical...
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Switch Sn Voltmeter Salt Bridge Wire Metal X 1.0 M Sn(NO₂)₂ 1.0 M X(NO₂), An electrochemical cell is constructed with an open switch, as shown in the diagram above. A strip of Sn and a strip of unknown metal, X are used as electrodes. When the switch is closed, the mass of the Sn electrode increases. The half-reactions are shown below. Sn²+ (aq) + 2e →→ Sn(s) E = -0.14 V E = ? X³+ (aq) + 3 e → X(s) (a) In the diagram above, label the electrode that is the cathode. Justify your answer. (b) In the diagram above, draw an arrow indicating the direction of electron flow in the external circuit when the switch is closed. (c) If the standard cell potential E cell is +0.60 V, what is the standard potential, in volts for the X³+/X electrode? (d) Identify metal X. (e) Write balanced net-ionic equation for the overall chemical reaction occurring in the cell. (f) In the cell, the concentration of Sn²+ is changed from 1.0 M to 0.50 M, and the concentration of X³+ is changed from 1.0 M to 0.10 M. (i) Substitute all appropriate values for determining the cell potential, Ecell, into the Nernst equation. (Do not do any calculations.) (ii) On the basis of your response in (f) (i), will the cell potential be greater than, less than, or equal to E cell? Justify your answer. Switch Sn Voltmeter Salt Bridge Wire Metal X 1.0 M Sn(NO₂)₂ 1.0 M X(NO₂), An electrochemical cell is constructed with an open switch, as shown in the diagram above. A strip of Sn and a strip of unknown metal, X are used as electrodes. When the switch is closed, the mass of the Sn electrode increases. The half-reactions are shown below. Sn²+ (aq) + 2e →→ Sn(s) E = -0.14 V E = ? X³+ (aq) + 3 e → X(s) (a) In the diagram above, label the electrode that is the cathode. Justify your answer. (b) In the diagram above, draw an arrow indicating the direction of electron flow in the external circuit when the switch is closed. (c) If the standard cell potential E cell is +0.60 V, what is the standard potential, in volts for the X³+/X electrode? (d) Identify metal X. (e) Write balanced net-ionic equation for the overall chemical reaction occurring in the cell. (f) In the cell, the concentration of Sn²+ is changed from 1.0 M to 0.50 M, and the concentration of X³+ is changed from 1.0 M to 0.10 M. (i) Substitute all appropriate values for determining the cell potential, Ecell, into the Nernst equation. (Do not do any calculations.) (ii) On the basis of your response in (f) (i), will the cell potential be greater than, less than, or equal to E cell? Justify your answer.
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Related Book For
Materials Science and Engineering An Introduction
ISBN: 978-0470419977
8th edition
Authors: William D. Callister Jr., David G. Rethwisch
Posted Date:
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