Question: W. Deng and K. W. Hipps (J. Phys. Chem. B 2003, 107, 10736-10740) reported an STM study of the electronic properties of Ni(ll)tetraphenyl porphyrin (NiTPP),

W. Deng and K. W. Hipps (J. Phys. Chem. B 2003, 107, 10736-10740) reported an STM study of the electronic properties of Ni(ll)tetraphenyl porphyrin (NiTPP), a red-purple, neutral diamagnetic complex that is made by reacting Ni(II) perchlorate with tetraphenylporphine.

When NiTPP is reacted with sodium thiocyanate it forms another complex that is paramagnetic. Draw the structures of NiTPP and the product complex, and the crystal field energy level diagram that explains each. What value of the magnetic moment (in units of MB) would you expect for the paramagnetic complex?

Step by Step Solution

★★★★★

3.42 Rating (155 Votes )

There are 3 Steps involved in it

1 Expert Approved Answer

Step: 1 Unlock

The structures of NITPP and the product complex NiNa2TPPSCN2 can be drawn as foll... View full answer

Question Has Been Solved by an Expert!

Get step-by-step solutions from verified subject matter experts

Step: 2 Unlock

Step: 3 Unlock

Students Have Also Explored These Related Accounting Questions!

Draw the structures of an I U wobble pair and an I C wobble pair.

Draw the structures of compounds A to D: NaNH, NaNH, 1) Excess NaNH, Br2 Br2 2) H20 (C3H12)

Draw the structures of the activated carbon groups bound to thiamine pyrophosphate in three enzymes that contain this coenzyme.

Silylene (SiH2) is a key intermediate in the thermal decomposition of silicon hydrides such as silane (SiH4) and disilane (Si2H6). Moffat et al. (H.K. Moffat, K.F. Jensen, and R.W. Carr, J. Phys....

There is some indication that other hydrogen ring compounds and ions in addition to H3 and D3 species may play a role in interstellar chemistry. According to J.S. Wright and G.A. DiLabio (J. Phys....

J.G. Dojahn, E.C.M. Chen, and W.E. Wentworth (J. Phys. Chem. 100, 9649 (1996)) characterized the potential energy curves of the ground and electronic states of homo nuclear diatomic halogen anions....

J.J Dannenberg, D. Leotard, P. Hal Vick, and I.C. Rayez (J. Phys. Chem. 100, 9631 (996)) carried out theoretical studies of organic molecules consisting of chains of unsaturated four-membered rings....

G.C.G. Wachewsky, R. Horansky, and V. Vaida (J. Phys. Chem. 100, 11559 (1996)) examined the UV absorption spectrum ofCH3I, a species of interest in connection with stratospheric ozone chemistry. They...

R. Viswanathan, R.W. Schmude, Jr., and K.A. Gingerich (J. Phys. Chem. 100,10784 (1996)) studied thermodynamic properties of several boron-silicon gas-phase species experimentally and theoretically....

T. Gierczak, R.K. Talukdar, S.C. Herndon, G.L. Vaghjiani, and A.R. Ravish Ankara (J. Phys. Chem. A 101, 3125 (1997)) measured the rate constants for the bimolecular gas-phase reaction of methane with...

Use synthetic division to find the function values. Then check your work using a graphing calculator. a. f (x) = x3 - 6x2 + 11x - 6; find f (1), f (- 2), and f (3). b. f (x) = x3 + 7x2 - 12x - 3;...

Sales in a company are $196 million in 2013 and increase to $198 million in 2014. a. Compute the percentage increase in sales, using the usual formula (Sales2014 Sales2013) Sales2013 100 x Compare...

The pluralist model of power relations in the U . S . suggests that Question 4 0 options: 1 ) power is concentrated in the hands of a small group of military, corporate, and political leaders. 2 )...

A Boolean formula is a Boolean circuit wherein every gate has only one output wire. The same input variable may appear in multiple places of a Boolean formula. Prove that a language has a polynomial...

The Canadian Institute of Chartered Accountants (cica.ca/index.aspx) provides standards and guidance for new issues, and solicits comments for new policies. Click on Whats New and pick one item from...

Go to the Web sites of Heritage Foundation (http://www.heritage.org/index/) and International Country Risk Guide (http://www.prsgroup.com/icrg/icrg.html). These sites provide information related to...

Construct a 23 design with ABC confounded in the first two replicates and BC confounded in the third. Outline the analysis of variance and comment on the information obtained.

Find J and K in the rotational system shown in Figure P4.21 to yield a 30% overshoot and a settling time of 3 seconds for a step input in torque. T) K FIGURE P4.21

A TA for a psychology class hosts one office session per week to help students. The office session is 2 hours long. It is estimated that an average of 10 students will come to the TA's office session...

DDE 12C X PDi Clas X G jjl x /// jill x E Den X Wo X |W Put X *Pro X ManageE E Search To Homewo + X File | C:/Users/HP/Downloads/Probability_Distribution_Investigation_Part_1%20(1).pdf G aliball ulj...

Scenario (90 minutes) Printing Plus Inc. (PPI) is a small social enterprise that provides a variety of printing services. PPI provides hands-on job experience for at-risk youth while also providing...

1 Multivariable functions and vector geometry Due date and time: Wednesday, June 7th at 9:30 AM in lecture Please ensure that you have read and understood the document \"Homework Guidelines" on the...

C++ / g++ all you have to do is complete the missing code - the missing subroutines for performing splay tree operations (SplayTreeMapclass) -the missing subroutines for performing inventory...

DATA STRUCTURES - AVL AND SPLAY TREES 2. [14 pts.] In this problem, you will consider pseudocode for algorithms to implement an ordered map ADT (abstract data type) using a general binary search tree...

coding in c++ Prompt for user input, and count and display the letter frequencies for the user input, adding this code to main.cpp. Then again display the sorted letters for each language, this time...