Molecular Spectroscopy 2nd Edition Jeanne L McHale - Solutions

How can combination bands be accounted for within the Kramers−Heisenberg−Dirac formula?
The correlation function for vibrational relaxation 〈QQ(t)〉 can be written in second quantized form, using dimensionless normal coordinateswhere [a, a+] = 1. (a) Show that the Heisenberg representations of the operators a and a+ are Q=(a¹ + a)/√√2,
(a) Using a bulk plasmon frequency ♄ωp of 9 eV, account for the background permittivity εb (assumed to be real) that leads to a surface plasmon resonance ♄ωR of 2.4 eV(b) Assuming ωp/T is on the order of 10, use the result from part (a) to find the value of the relative permittivity at the

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