Tertiary alkyl halides, R 3 CX, undergo spontaneous dissociation to yield a carbocation, R 3 C +

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Tertiary alkyl halides, R3CX, undergo spontaneous dissociation to yield a carbocation, R3C+, plus halide ion. Which do you think reacts faster, (CH3)3CBr or H2C = CHC (CH3)2Br? Explain.

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