Question: The compound (mathrm{NO}_{2} mathrm{Cl}) is thought to decompose to (mathrm{NO}_{2}) and (mathrm{Cl}_{2}) by the following mechanism: Derive the rate law for the production of (mathrm{Cl}_{2})

The compound \(\mathrm{NO}_{2} \mathrm{Cl}\) is thought to decompose to \(\mathrm{NO}_{2}\) and \(\mathrm{Cl}_{2}\) by the following mechanism:

NOCl NOCI+ CI k_1 NO + Cl NO + Cl

Derive the rate law for the production of \(\mathrm{Cl}_{2}\) using the steady-state approximation.

NOCl NOCI+ CI k_1 NO + Cl NO + Cl

Step by Step Solution

★★★★★

3.48 Rating (148 Votes )

There are 3 Steps involved in it

1 Expert Approved Answer
Step: 1 Unlock

The steadystate approximation is a useful tool in chemical kinetics for simplifying reaction mechani... View full answer

blur-text-image
Question Has Been Solved by an Expert!

Get step-by-step solutions from verified subject matter experts

Step: 2 Unlock
Step: 3 Unlock

Students Have Also Explored These Related Chemical Principles Questions!

Q:

Hydrogen radicals are important to sustaining combustion reactions. Consequently, if chemical compounds that can scavenge the hydrogen radicals are introduced, the flames can be extinguished. While...

Q:

One of the major reasons for engineoil degradation is the oxidation of the motor oil. To retard the degradation process, most oils contain an antioxidant. Without an inhibitor to oxidation present,...

Q:

Titanium dioxide is a wide-bandgap semiconductor that is showing promise as an insulating dielectric in VLSI capacitors and for use in solar cells. Thin films of TiO2 are to be prepared by chemical...

Q:

For the following equilibrium reaction, determine the expression for the concentration of \( \mathrm{NO}_{2} \). \[ \mathrm{NO}_{2} \mathrm{Cl}(g)-\mathrm{NO}_{2}(g)+\mathrm{Cl}(g) \] (a) \(...

Q:

\(100.0 \mathrm{kmol} / \mathrm{h}\) of a saturated vapor feed that is \(25.0 \mathrm{~mol} \%\) nitromethane (NM) and \(75.0 \mathrm{~mol} \%\) water is separated in a system with two distillation...

Q:

We are separating nitromethane and water in a distillation system consisting of two columns, two total condensers, two partial reboilers, and a liquid-liquid separator. CMO is valid, and \(p=1.0...

Q:

Nitromethane and water are separated in a rectifying column system with a total condenser and a liquid-liquid settler similar to Figure 8-3A, except the column is a rectifying column. The saturated...

Q:

a. Based on the data in Table \(17-1\), rank the cations \(\left(\mathrm{NH}_{4}, \mathrm{Ba}, \mathrm{Ca}, \mathrm{Cu}, \mathrm{Mg}, \mathrm{Mn}, \mathrm{Ni}, \mathrm{K}, \mathrm{Na} ight)\) in...

Q:

The balance sheet for Ronlad Corporation reported 188,000 shares outstanding, 285,000 shares authorized, and 19,000 shares in treasury stock. Compute the maximum number of new shares that the company...

Q:

Lee Technical Services Inc. was established on June 15, 2008. The clients for whom Lee provided technical services during the remainder of June are listed below. These clients pay Lee the amount...

Q:

The 2014 populations and land areas are shown in Table 28 for various states. Round all unit ratios to the second decimal place: a. Find the unit ratio of New Yorks population to New Jerseys...

Q:

Which of the following situations would most likely be observed on the statement of cash flow for a start - up company? Operating Cash Flow Investing Cash Flow Financing Cash Flow A . Negative...

Q:

In February, Brush Company contracts to paint Josephs house. The house is painted in March, and Joseph pays Brush Company in April. Brush Company should recognize revenue in (what month?).

Q:

Draw the Lewis structure and give the approximate bond angles of (a) C 2 H 4 ; (b) ClCN; (c) OPCl 3 ; (d) N 2 H 4 .

Q:

Hypochlorous acid, HClO, is found in white blood cells, where it helps to destroy bacteria. Draw two Lewis structures with different atom arrangements for HClO and select the most likely structure by...

Q:

The perchlorate ion, ClO 4 , is described by resonance structures. (a) Draw the Lewis structures that contribute to the resonance hybrid and identify the most plausible Lewis structures by using...

Q:

What is a forward exchange rate? When does deliv- ery occur on a 90-day forward contract?

Q:

Consider the following independent situations: (i) Archie Andrews, public accountant, performs the audit as well as prepares the tax returns and performs various management services for Mercury Ltd....

Q:

hedef gelir u anlama gelir: A. Baaba noktasndaki gelir B. Son dneme ait gelir C. Gelecek bir dnem iin planlanan gelir D. Yalnzca oklu rn ortamnda gelir E. Asgari katk payndaki gelir