The following data are raw data from the ARSST. Assume a first-order reaction for this system. The

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The following data are raw data from the ARSST. Assume a first-order reaction for this system. The heating rate for the calorimeter is \(0.3^{\circ} \mathrm{C} / \mathrm{min}\).

a. Plot the temperature rate versus \(-1000 / T\) to estimate the detected onset and final temperatures.

b. Use Equation 8-31 to determine the kinetic parameters \(A\) and \(E\) a for the original raw data.

In dT/ dt TF-T = In A - Ea RgT (8-31)

Time (min) 0 5.1 10.1 15.2 20.2 25.3 30.3 35.4 40.4 45.5 50.6 55.6 60.7 65.7 70.7 75.8 80.8 85.9 90.9 95.1

Time (min) 98.25 99.2 99.53 99.63 99.75 99.87 99.93 100.01 100.06 100.13 100.21 100.3 100.39 100.48 101.2

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