In a process analysis application, you are working with the di-n-propyl ether (1) and 2-propanol (2) system

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In a process analysis application, you are working with the di-n-propyl ether (1) and 2-propanol (2) system at 25°C. You think you have an error in the spread sheet you have been working with, but you can’t seem to find the problem. After a while, you begin to wonder if the data you are using is thermodynamically consistent. Not that you are suspicious of the data, but you’ve checked everything else by this point.

T TI H     H_C_C-C-0-C-C-C-H HTCIH    || TI    Di-n-propyl ether

CH3-CH-CH3 OH 2-propanol

For the data presented in Table P11-29, examine the thermodynamic consistency using both the integral test and direct test.

TABLE P11-29 Vapor-liquid equilibrium of di-n-propyl ether (1) + 2-propanol (2) at 298.15 K. P[kPa] 2.878

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