Question: Refer to Example 12-12. Together with data given there, use the data here to calculate f H for 1 mol MgCl 2 (s). Explain

Refer to Example 12-12. Together with data given there, use the data here to calculate ΔfH° for 1 mol MgCl2(s). Explain why you would expect MgCl2 to be a much more stable compound than MgCl. (The second ionization energy of Mg is 1451 kJ mol-1; the lattice energy of MgCl2(s) is -2526 kJ mol-1 MgCl2.)

Example 12-12

With the following data, calculate ΔfH° of MgCl(s): Enthalpy of sublimation of Mg(s): +146 kJ mol-1; enthalpy of dissociation of Cl2(g): +244 kJ mol-1; first ionization energy of Mg(g): +738 kJ mol-1; electron affinity of Cl(g): -349 kJ mol-1; lattice energy of MgCl(s): -676 kJ mol-1.

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To calculate fH for 1 mol MgCl2s use the BornHaber cycle Mgs Cl2g MgCl2s Hf 641 kJmol Using the data ... View full answer

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