The activity of a pure solid or liquid is approximately where V is the molar volume. For
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The activity of a pure solid or liquid is approximately
![a = "V(P - P)` P] RT expl](https://dsd5zvtm8ll6.cloudfront.net/images/question_images/1700/4/8/4/480655b5580188e01.png)
where V̅ is the molar volume. For a pure solid or liquid under typical conditions, the quantity V̅(P - P°)/(RT) is quite small, primarily because V̅ is small, and so a ≈ 1. Use the following data, for liquid water at 300 K, to verify that a ≈ 1 over a wide range of pressures.
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Related Book For 
General Chemistry Principles And Modern Applications
ISBN: 9780132931281
11th Edition
Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette
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