In the fabrication of semiconductors, one step is the formation of additional gallium arsenide (GaAs) on the

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In the fabrication of semiconductors, one step is the formation of additional gallium arsenide (GaAs) on the surface of a GaAs wafer. To accomplish this, gaseous tri-methyl gallium (TMG) and arsine flow in a carrier gas (usually hydrogen) over the solid and react on the solid surface at a temperature of 900K to produce the solid GaAs and gaseous methane. The unreacted TMG and arsine and the newly produced methane flow out in the outlet gas.

Ga(CH3)3(g) TMG + AsH3(g)  GaAs(s) + 3CH4 (g) Arsine Methane

This process can be treated as a steady-state process wherein the deposition of the solid is treated as an outlet stream of pure solid GaAs. For such a process, the following are given:

Gas In Stream Flow Rate 8.5 L/min Components TMG, arsine, H Gas Out 8.5 L/min TMG, arsine, H, CH4 Solid where the quantity in the solid “out” indicates that we wish to deposit 7 mg/min of GaAs. Also, we have assumed that the flow rate of the gas stream doesn’t change significantly.
What is the concentration of methane in the outlet gas?

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