Question: Possible correlating equations for ln 1 in a binary liquid system are given here. For one of these cases, determine by integration of the
Possible correlating equations for ln γ1 in a binary liquid system are given here. For one of these cases, determine by integration of the Gibbs/Duhem equation [Eq. (13.11)] the corresponding equation for ln γ2. What is the corresponding equation for GE∕RT? Note that by its definition, γi = 1 for xi = 1.
(a) ln γ1 = A x22 ;
(b) ln γ1 = x22 (A + B x2);
(c) ln γ1 = x22 (A + B x2 + C x22) ;
Eq. (13.11)
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Ex;d Iny; = 0 (const T, P) (13.11) i
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