Suppose the reaction in Problem 14.105 goes to completion. What must be true about E a for

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Suppose the reaction in Problem 14.105 goes to completion. What must be true about Ea for the forward reaction relative to Ea for the reverse reaction?


Data from Problem 14.105

Suppose the reaction A2 + B2 ⇆ 2 AB proceeds via a one-step mechanism involving a collision between one A2 molecule and one B2 molecule. Suppose also that this reaction is reversible, and that the forward reaction is inherently much faster than the reverse reaction.

(a) Does the equilibrium lie to the left or to the right? Explain your choice in terms of the reactant and product concentrations necessary to establish equal forward and reverse rates.

(b) Does an analysis in terms of the relationship Keq = kf/kr yield the same answer as in (a)? Explain.

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Related Book For  answer-question

Introductory Chemistry Atoms First

ISBN: 9780321927118

5th Edition

Authors: Steve Russo And Michael Silver

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