Give the major organic product of each of the following reactions. Include stereochemistry where relevant. (a) Dibutyl

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Give the major organic product of each of the following reactions. Include stereochemistry where relevant.

(a) Dibutyl sulfide with 1 equivalent of H2O2 at 25°C

(b) Dibutyl sulfide with 2 or more equivalents of H2O2 and heat

(c) Cis-3-hexene with magnesium monoperoxyphthalate (MMPP)

(d) The product of (c) with (CH3)2CuCNLi2, then H3O+

(e) The product of (c) with solvent H2O in acidic solution

(f) The product of (e) with periodic acid

(g) The product of (d) with NaH in THF followed by CH3I

(h) (E)-3-methyl-3-hexene with Hg(OAc)2 in ethanol solvent followed by NaBH4

(i) The product of (h) with acidic methanol

(j) (R)-3-Methyl-1-bromopentane with Mg in ether, then with ethylene oxide, then with CH3I

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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