In this problem you will derive the commutator [lx, ly] = ihlz. a. The angular momentum vector

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In this problem you will derive the commutator [l̂x, l̂y] = ihl̂z.

a. The angular momentum vector in three dimensions has the form l = ilx + jly + klz, where the unit vectors in the x, y, and z directions are denoted by i, j, and k. Determine lx , ly , and lz by expanding the 3 × 3 cross product l = r × p. The vectors r and p are given by r = i x + j y + k z and p = i px + j py + k pz .

b. Substitute the operators for position and momentum in your expressions for lx and ly. Always write the position operator to the left of the momentum operator in a simple product of the two.

c. Show that [l̂x, l̂y ] = ihl̂z .

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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