The chlorination of vinyl chloride, C 2 H 3 Cl + Cl 2 C 2 H 3

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The chlorination of vinyl chloride, C2H3Cl + Cl2†’ C2H3Cl3, is believed to proceed by the following mechanism:

Cl2-2C1. Cl. + C2H3CI- С Н.С1,-+ Cl, — сн,C + —Сн.Cl. Cl. →stable species СН.С1,.+ Снс1,.—

Derive the rate law expression for the chlorination of vinyl chloride based on this mechanism.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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