Question: 1 2 . 2 8 Consider a closed vessel initially containing 1 mol of pure tetrahydrofuran at 7 4 oC and 1 2 0 kPa.

12.28 Consider a closed vessel initially containing 1 mol of pure tetrahydrofuran at 74oC and 120 kPa. Imagine that pure chloroform is slowly added at constant temperature and pressure until the vessel contains 1 mol tetrahydofuran and 9 mol chloroform. Describe the evolution of phases and phase compositions during this process. Comment on the practical feasibility of carrying out such a process. What sort of device would be required ? How would the total system volume change during this process ? At what composition would the system volume reach its maximum value?

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