Question: 1. Select the compound that can be prepared using acetoacetic acid synthesis? 2. What is the product? 3. What is the product? 4. Show the

1. Select the compound that can be prepared using acetoacetic acid synthesis?

2. What is the product?

2. What is the product? 3. What is the product? 4. Show

3. What is the product?

the mechanism including all intermediates 5. What is the product? 6. What

4. Show the mechanism including all intermediates

is the product? 7. What is the full Robinson Annulation product including

5. What is the product?

all intermediates? 8. Show mechanism including all intermediates 9. Fill in the

6. What is the product?

products for each step O Qui ui . O OEt 1. NaOELHOE

7. What is the full Robinson Annulation product including all intermediates?

2. H30*, Heat OET 1. 1.1 equiv. NaoFt/HOET 2. H,O*Heat Bry +

8. Show mechanism including all intermediates

NaOELHOET O Nao Et/HOE O 0 1. NaOET/HOEt Eto OEt 2. H2O+/

9. Fill in the products for each step

Heat 0 i 1. NaOEU/HOEt + 2. H20*/ Heat 1. NaOEU/HOEt OEt

O Qui ui . O OEt 1. NaOELHOE 2. H30*, Heat OET 1. 1.1 equiv. NaoFt/HOET 2. H,O*Heat Bry + NaOELHOET O Nao Et/HOE O 0 1. NaOET/HOEt Eto OEt 2. H2O+/ Heat 0 i 1. NaOEU/HOEt + 2. H20*/ Heat 1. NaOEU/HOEt OEt 2. H307/heat 1. NaOEVHOE 1. LDA dehydration 2. CH3CH2Br (Ph)2Culi o PhCH2PPh3 B NaOH MCPBA H30* Eto 1. Nah ELO 2. CH3CH21

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