Arrange the following: (i) In decreasing order of the pK,values: C.H.NH., C.H.NHCH,, (CH.).NH and C.H.NH, (ii)...

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Arrange the following: (i) In decreasing order of the pK,values: C.H.NH., C.H.NHCH,, (CH.).NH and C.H.NH, (ii) In increasing order of basic strength: C.H.NH, C.H.N(CH), (C,H,),NH and CH,NH, (iii) In increasing order of basic strength: (a) Aniline, p-nitroaniline and p-toluidine (b) CH,NH,, CH,NHCH, CH,CHNH (iv) In decreasing order of basic strength in gas phase: C.H.NH., (C.H.),NH, (C.H.),N and NH, (v) In increasing order of boiling point: C.H.OH, (CH.).NH, C.H.NH, (vi) In increasing order of solubility in water: CH.NH., (C.H.).NH, CHNH.. Arrange the following: (i) In decreasing order of the pK,values: C.H.NH., C.H.NHCH,, (CH.).NH and C.H.NH, (ii) In increasing order of basic strength: C.H.NH, C.H.N(CH), (C,H,),NH and CH,NH, (iii) In increasing order of basic strength: (a) Aniline, p-nitroaniline and p-toluidine (b) CH,NH,, CH,NHCH, CH,CHNH (iv) In decreasing order of basic strength in gas phase: C.H.NH., (C.H.),NH, (C.H.),N and NH, (v) In increasing order of boiling point: C.H.OH, (CH.).NH, C.H.NH, (vi) In increasing order of solubility in water: CH.NH., (C.H.).NH, CHNH..

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