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The specific heat capacity was calculated for the materials based on the Neumann$-$Kopp rule $($NKR$)$ for mixtures $[19]$:

$Cp={\displaystyle \underset{i=1}{\overset{n}{}}}{?}_{ci.f_i}$

Where, $C_i$ is the specific heat capacity of the component and $f_i$ is the mass fraction of that component. The temperature dependent

values of $C_p$ were converted from the molar heat capacity calculated for Mo using the Shomate equation with constants from Chase

$[20]$ and for $U{O}_2$ from Fink et al$.[3].$ For comparison, at $298K$ the $C_p$ for $Mo$ and $U{O}_2$ are $244\mathrm{.}5$ and $296\mathrm{.}7\frac{J}{g}.K$ respectively. The

thermal conductivity was normalised to $95\%TDU{O}_2$ utilising the relationship proposed by Brandt and Neuer $[21]$;

${}_0=\frac{{}_p}{1-(2\mathrm{.}6-0\mathrm{.}5t)P}$

where ${}_0$ is the thermal conductivity at theoretical density, ${}_p$ is the thermal conductivity at a given porosity, $P$ is the fraction of

porosity in the $U{O}_2$ and $t$ is $\frac{T}{1000},$ where $T$ is the absolute temperature.