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6. Work through Example 14-10A from the text (not homework section), and complete the following items: a. Complete the stoichiometric table b. Calculate the equilibrium constant c. Calculate the extent of reaction d. Calculate the mole fraction of all components e. Do you think the reaction would shift more towards the products or the reactants if methane and chlorine were fed in equimolar quantities? Explain your answer. f. Do you think the reaction would shift more towards the products or the reactants if the pressure was increased to 5 bar? Explain your answer. EXAMPLE 14-10 SEQUENTIAL CHLORINATION OF METHANE Chloroform (CHCI) Example 14-8 illustrated the chlorination of methane to form chloromethane: and carbon ter (R1): chloride (CCI) are CH,+ CICHA+HCI common names Example 14-8 also revealed that at equilibrium, the products were strongly favored that predate IUPAC However, the substitution of chlorine for hydrogen can continue in subsequent reactions, nomenclature. The IUPAC names are forming dichloromethane, chloroform, and carbon tetrachloride: trichloromethane and (R2) tetrachloromethane CH,CI + a, -- CH CI, + HCI (R3) CHC + C6 CHO + HC (R4): CHCI, + a, +CC), + HCI A steady-state reactor is maintained at P1 bar and 7 - 1000'C. Assuming the prod. uct stream leaving the reactor is at equilibrium, find its composition if the reactor feed consists of the following A. 1 mol/s of methane and 4 mol/s of chlorine B. 1 mols of methane and 1 molls of chlorine Use the shortcut method to account for the effects of temperature, Methane 1 mois Steady-state reactor T-1000'C, P-1 Chlorine 4 mol/s (a) Methane 1 mol/s Steady-state reactor T-1000'C, P-1 bar Chlorine 1 molts [b] FIGURE 14- Chlorination of methane as modeled in Example 14.10. CI, CH,CI, CHCI Total CCI, 5 TABLE 14-15 Stoichiometric table for sequential chlorination of methane, part A CH, CHCI HCI In (mol/s) 1 4 Gen, Ri (mol/s) -&, + Gen, R2 -5, +, (mol/s) Gen, R3 -6 + (mol/s) + + 0 +5, 0 Gen, R4 (mol/s) - + + Out (mol/s) 4 1-4, 4-6, - , - & -. $ - . $ + 6 + 6 + 6,- , 6, - . & - , 1 - 4-6, - $, - , - , + 5 5 5 5 5 5 5 5