Please solve both questions

A liquid phase reaction, A+BC+D is to be carried out in a well-mixed ideal batch reactor with a constant volume of 10 liters. The initial concentration of A is 6.58mol/L, and the initial concentration of B is one half of the initial concentration of A. If the rate of formation of compound D is given by rD= kCACB, with k=4.5L/(molmin), calculate the amount of time (in minutes) needed to achieve a conversion of the limiting reactant of 0.95. Please express your answer to two decimal places. Hint: Remember to determine the limiting reactant! The isomerization reaction A>B is to take place in an ideal packed bed reactor. The volumetric flow rates in and out are equivalent at 5.0 L/min. The rate law only depends on the rate constant and the concentration of A, and the rate of destruction of A(rA) is equal to kCA, where k=0.8L/(ming). The inlet concentration of A is 15M (note that M= mol/L ), what is the amount of catalyst (in grams,g) required to reach a final concentration of 0.2M ? Please provide your answer as an integer. Thus 10.3 would be entered as 10 and 10.6 would be entered as 11