Question: The rate expression below has been obtained from reactor tests for the low temperature decomposition of ozone that is catalyzed by chlorine. d[03]/dt = -k[Cl2]0.5[O3]1.5

 The rate expression below has been obtained from reactor tests for

The rate expression below has been obtained from reactor tests for the low temperature decomposition of ozone that is catalyzed by chlorine. d[03]/dt = -k[Cl2]0.5[O3]1.5 You have proposed the following mechanism (sequence of elementary steps) for this reaction: CIO + CIO: ki Cl2 + 03 k2 ClO2 + 03 103. + O2 k3 CIOz. + 03 CIOz. + 202 ka 2C1Oz. + Cl2 + 302 ks 2CIO. Cl2 + O2 Using the Steady State Approximation, what rate expression results from this mechanism? Is the expression from the SSA consistent with the equation derived from experimentation? Assume that the term representative of the initiation step is negligible

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