Consider a mixture of water and salt with a low salt concentration. Use the ideal mixture law

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Consider a mixture of water and salt with a low salt concentration. Use the ideal mixture law (8.68) to evaluate the chemical potential of water in the salt solution. Recall that according to relation (8.51), for any substance A in any given phase, μA (T) = hA − T sA. Assume that near the boiling temperature T0 of pure water, the molar enthalpy hA and the molar entropy sA of the liquid and vapour phases do not depend on temperature. Determine the boiling temperature variation T − T0 as a function of salt concentration cA.

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Principles Of Thermodynamics

ISBN: 9781108426091

1st Edition

Authors: Jean-Philippe Ansermet, Sylvain D. Brechet

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