Question: Use the Gibbs-Duhem equation to show that the partial molar volume (or any partial molar property) of a component B can be obtained if the

Use the Gibbs-Duhem equation to show that the partial molar volume (or any partial molar property) of a component B can be obtained if the partial molar volume (or other property) of A is known for all compositions up to the one of interest. Do this by proving that Use the following data (which are for 298 K) to evaluate the integral graphically to find the partial molar volume of acetone at x = 0.500.
X (CHCI3) 0 0.194 0.385 0.559 0.788 0.889 1.000
Vml (cm3 mol-1) 73.99 75.29 76.50 77.55 79.08 79.82 80.67

Step by Step Solution

3.47 Rating (170 Votes )

There are 3 Steps involved in it

1 Expert Approved Answer
Step: 1 Unlock

nad VA nBdVB 0 Example 51 NA Hence dVA dVB nB Therefore ... View full answer

blur-text-image
Question Has Been Solved by an Expert!

Get step-by-step solutions from verified subject matter experts

Step: 2 Unlock
Step: 3 Unlock

Document Format (1 attachment)

Word file Icon

57-C-PC-E (142).docx

120 KBs Word File

Students Have Also Explored These Related Physical Chemistry Questions!