In Figure 13-5 the temperature dependence of the standard molar entropy for chloroform is plotted. (a) Explain

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In Figure 13-5 the temperature dependence of the standard molar entropy for chloroform is plotted.

(a) Explain why the slope for the standard molar entropy of the solid is greater than the slope for the standard molar entropy of the liquid, which is greater than the slope for the standard molar entropy of the gas. 

(b) Explain why the change in the standard molar entropy from solid to liquid is smaller than that for the liquid to gas.

Figure 13-5

Standard molar entropy, J mol-1 K-1 250 200 150 100 50 50 Solid 100 Liquid (s) + (1) 150 Temperature, K 200

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General Chemistry Principles And Modern Applications

ISBN: 9780132931281

11th Edition

Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette

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