(a) As shown in Fig. P11.78(a), 1,5-cyclooctadiene undergoes an electrophilic addition with SCl2 to give compound A....
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(a) As shown in Fig. P11.78(a), 1,5-cyclooctadiene undergoes an electrophilic addition with SCl2 to give compound A. (Notice the conformation of A, also shown.) Provide a curved-arrow mechanism for this transformation that accounts for the stereochemistry.
(b) Suggest a mechanism that accounts for the reaction of A shown in Fig. P11.78(b).
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a b An episulfonium ion analogous to a bromonium ion X is formed at one double bond r...View the full answer
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