Question: Derive the rate law ( - rc ) for the given below multiple reactions with an assumption that surface reaction rate constant for first reaction

Derive the rate law (-rc) for the given below multiple reactions with an assumption that surface reaction rate constant for first reaction is very small as compared to the adsorption and desorption step. Consider external and internal mass transfer resistance as negligible and the reaction follows Langmuir-Hinshelwood kinetics model.
A+BC+D
2AE+D
 Derive the rate law (-rc) for the given below multiple reactions

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