Question: The reaction CO 2 (aq) + OH - (aq) --> CO 3 2- (aq) + H 2 O(l) proceeds through the following mechanism: CO 2

The reaction CO2(aq) + OH-(aq) --> CO32-(aq) + H2O(l) proceeds through the following mechanism:

CO2(aq) + OH-(aq) --> HCO3-(aq) HCO3-(aq) + OH-(aq) --> CO32-(aq) + H2O(l)

(a) The first step of this mechanism is rate-determining (slow). What is the rate law for this reaction?

Rate = k [CO2] [OH-]Rate = k [CO2]2 [OH-] Rate = k [CO2] [OH-]2Rate = k [CO2]1/2 [OH-]Rate = k [CO2] [OH-]1/2Rate = k [CO2]2Rate = k [CO2]2 [OH-]1/2

(b) What would the rate law be if the second step of this mechanism were rate-determining?

Rate = k [CO2] [OH-]Rate = k [CO2]2 [OH-] Rate = k [CO2] [OH-]2Rate = k [CO2]1/2 [OH-]Rate = k [CO2] [OH-]1/2Rate = k [CO2]2Rate = k [CO2]2 [OH-]1/2Rate = k [CO2]

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