The data in the following table have been obtained for the potential of the cell Pt(s) |H

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The data in the following table have been obtained for the potential of the cell Pt(s) |H2(g, f = 1atm) HCl(aq, m)|AgCl(s) Ag(s) as a function of m at 25°C.

m (mol kg) m (mol kg) m (mol kg-l) E (V) 0.57915 0.54425 0.49846 E (V) E (V) 0.27231 0.23328 0.20719 0.500 0.00100 0.020

a. Determine E° using a graphical method.

b. Calculate γ ± for HCl at m = 0.00100, 0.0100, and 0.100 mol kg–1.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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