The data in the following table have been obtained for the potential of the cell Pt(s) H 2 (g, f 1atm) HCl(aq, m) AgCl(s) Ag(s) as a function of m at 25C a Determine E using a graphical method b Calculate for HCl at m 0 00100, 0 0100, and 0 100 mol kg 1 m (mol kg) m (mol kg) m (mol kg l) E (V) 0 57915 0 54425 0 49846 E (V) E (V) 0 27231 0 23328 0 20719 0 500 0 00100 0 0200 0 43024 0 38588 0 35241 0 00200 0 0500 1 000 0 00500 0 0100 1 500 2 000 0 100 0 200 0 46417 0 31874 0 18631

Question: The data in the following table have been obtained for the potential of the cell Pt(s) |H 2 (g, f = 1atm) HCl(aq, m)|AgCl(s) Ag(s)

The data in the following table have been obtained for the potential of the cell Pt(s) |H₂(g, f = 1atm) HCl(aq, m)|AgCl(s) Ag(s) as a function of m at 25Â°C.

m (mol kg) m (mol kg) m (mol kg-l) E (V) 0.57915 0.54425 0.49846 E (V) E (V) 0.27231 0.23328 0.20719 0.500 0.00100 0.020

a. Determine EÂ° using a graphical method.

b. Calculate Î³ _Â± for HCl at m = 0.00100, 0.0100, and 0.100 mol kg^â€“1.

m (mol kg) m (mol kg) m (mol kg-l) E (V) 0.57915 0.54425 0.49846 E (V) E (V) 0.27231 0.23328 0.20719 0.500 0.00100 0.0200 0.43024 0.38588 0.35241 0.00200 0.0500 1.000 0.00500 0.0100 1.500 2.000 0.100 0.200 0.46417 0.31874 0.18631

Step by Step Solution

★★★★★

3.33 Rating (150 Votes )

There are 3 Steps involved in it

1 Expert Approved Answer

Step: 1 Unlock

Cell reaction 2AgCls H 2 g2Ags 2H aq 2Cl aq In the low ... View full answer

Question Has Been Solved by an Expert!

Get step-by-step solutions from verified subject matter experts

Step: 2 Unlock

Step: 3 Unlock

Students Have Also Explored These Related Physical Chemistry Questions!

After engaging with Money Quest: Choose Your Challenge, reflect on how financial literacy impacts real-life decision-making. Choose one of the following prompts to guide your discussion: Based on...

The following data have been obtained for oxygen gas at 273.15 K. Calculate the best value of the gas constant R from them and the best value of the molar mass of02 0.750000 0.250000 Platm 0.500000...

The following data have been obtained for the liquid-vapour equilibrium compositions of mixtures of nitrogen and oxygen at 100 kPa. T/K 77.3 78 80 82 84 86 88 90.2 X (O2) 0 10 34 54 70 82 92 100...

Your task in this problem will be to use a spreadsheet to generate a Txy diagram for a two-component system, using Raoult?s law to express the vapor?liquid equilibrium distribution of each species....

In one type of Breathalyzer (alcohol meter), the quantity of ethanol in a sample is related to the amount of electric current produced by an ethanoloxygen fuel cell. Use data from Table 19.1 and...

But you know that electrons can also flow through wires. So if we pick the same two reactants and place them in separate beakers with a wire connecting the two solutions, will electrons spontaneously...

Use data from Table 19.1, as necessary, to predict the probable products when Pt electrodes are used in the electrolysis of (a) CuCl 2 (aq); (b) Na 2 SO 4 (aq); (c) BaCl 2 (l); (d) KOH(aq). Table...

(A) Use data from Table 19.1 to predict the probable products when Pt electrodes are used in the electrolysis of KI(aq). Table 19.1 (B) In the electrolysis of AgNO 3 (aq), what are the expected...

Lab Report #12 - Voltaic Cells Measured cell potentials Edll (measured) 1,086 1.053 1.121 0.626 0.618 0.643 1.504 1. ZnZn?"(1.0M) Cu? (1.0M) Cu 2. ZnZn?"(1.0M) Cu (0.1 MOI CU 3. ZnZn0.1 M) || (1.0M)...

Use data from Table 19.1 to predict whether, to any significant extent, (a) Mg(s) will displace Pb 2+ from aqueous solution; (b) Sn(s) will react with and dissolve in 1 M HCl; (c) SO 4 2- will...

(A) Use data from Tables 19.1 and 23.4 to determine whether nitric acid can be used to oxidize V 3+ (aq) to VO 2+ (aq) for standard-state conditions. If so, write a balanced equation for the...

Despite strong arguments in favor of international diversification, international portfolio investment is still not widespread in many countries. One reason for this is the presence of barriers to...

"My company's equipment has been fully depreciated. But they can still function. What should we do?" A fully depreciated equipment means that the accumulated depreciation has reached the full...

Find h ' ( t ) if h ( t ) = 1 0 . 2 7 . 3 t - 0 . 7 t 2 . h ' ( t ) =

Lise Anderson opened a medical office under the name Lise Anderson, MD, on August 1, 2014. On August 31, the balance sheet showed Cash $3,000; Accounts Receivable$1,500; Supplies $600; Equipment...

If the value of a partnership is worth far more than the book value of the assets on the balance sheet, would a new partner entering the partnership be more likely to pay a bonus to the old partners...

On June 1, 2015, Demer Consulting provides services to a customer for $150,000. To pay for the services, the customer signs a three-year, 12% note. The face amount is due at the end of the third...

The Lux Company experiences the following unrelated events and transactions during Year 1. The company's existing current ratio is 2:1 and its quick ratio is 1.2:1. 1. Lux wrote off $5,000 of...

Refer to Cornerstone Exercises 2.2 and 2.3. Next year, Pietro expects to produce 50,000 units and sell 49,300 units at a price of $12.50 each. Beginning inventory of finished goods is $42,500, and...

3. The firm represented by Figure 11-2 (c) is a. making a normal profit. b. incurring a loss, once opportunity costs are considered. c. producing at the same level of output as a purely competitive...

Discuss the physical origins of the surface Gibbs energy.

The rate of sedimentation of a recently isolated protein was monitored at 20C and with a rotor speed of 50 000 r.p.m. The boundary receded as follows: Calculate the sedimentation constant and the...

Find the drift speed of a particle of radius 20 m and density 1750 kg m 3 which is settling from suspension in water (density 1000 kg m 3 ) under the influence of gravity alone. The viscosity of...

Player Pressure Aggression Defence Endurance Overall score Rafael Nadal 96 81 80 86 Novak Djokovic Roger Federer 87 94 89 67 Daniil Medvedev 85 81 94 80 Dominic Thiem 85 79 79 93 Stefanos Tsitsipas...

Essence of Skunk Fragrances, Ltd., sells 7,600 units of its perfume collection each year at a price per unit of $810. All sales are on credit with terms of 1.5/15, net 60. The discount is taken by 75...

The following gives information about the proportion of a sample that agree with a certain statement. Use StatKey or other technology to find a confidence interval at the given confidence level for...