A railcar is being splash filled with toluene. The car is \(38 \mathrm{~m}^{3}\) in volume, and the filling hole is \(0.10 \mathrm{~m}\) in diameter. It takes \(30 \mathrm{~min}\) to fill the rail car. Estimate the concentration of toluene in this vicinity if the ventilation rate is \(85 \mathrm{~m}^{3} / \mathrm{min}\). The temperature is \(25^{\circ} \mathrm{C}\) and the pressure is \(1 \mathrm{~atm}\).