When 1, 3-cyclopentadiene and maleic anhydride (Eq. 15.12a, p.698) are allowed to react at room temperature, a
Question:
Eq. 15.12a
(a) Show these transformations with equations, including the structures of all compounds.
(b) According to these observations, is the Diels-Alder reaction of maleic anhydride and 1, 3-cyclopentadiene at room temperature a kinetically controlled or a thermodynamically controlled reaction?
(c) Draw two diagrams like Fig. 15.8, p. 695, one showing the transition state that leads to the endo product, and the other showing the transition state that leads to the exo product. According to the data in this problem, which diagram portrays the transition state of the reaction at low temperature?
Fig. 15.8
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