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introductory chemistry atoms first
Questions and Answers of
Introductory Chemistry Atoms First
In which period and which group is the element that has the ground-state electron configuration 1s22s22p63s23p64s23d3? Which element is this?
In which period and which group is the element that has the ground-state electron configuration [Xe]6s1? Which element is this?
The alkali metals all react with water by giving up an electron to it. Based on their relative positions in the periodic table, which do you think would be more reactive with water, lithium or sodium?
Arrange the atoms Mg, Sr, S, O, and Rb from smallest to largest.
In the pie-chart graphs, the percent natural abundance for Cl-35 (atomic mass 34.969 amu) is represented as green, and the percent natural abundance for Cl-37 (atomic mass 36.966 amu) is represented
Give the full symbol for the atom or ion that has 26 protons and 30 neutrons in its nucleus, and 23 electrons outside its nucleus. Also give the number of the group this element is in.
Consider the following process (e– represents an electron):(a) Give the full symbol for the starting atom.(b) Give the full symbol for the resulting ion.(c) Is the product a cation or an anion?
Fill in the blanks for each of the atoms below (protons are red, neutrons are blue, and electrons are black): Element Ion (yes or no) Charge of atom Atomic number Mass number ||| |||| ||
The following is a periodic table consisting only of the representative elements. Indicate where the transition metals get inserted. How many groups are in the smaller section of representative
The U.S. quarter, pictured below, has a diameter of 24.25 mm. If the nucleus inside an atom had the diameter of a U.S. quarter, then what would be the diameter of the atom in miles? RE
Although not discussed until the next chapter, what process do you think chemists mean by an atom’s second ionization energy?
Regarding problem 3.137, do you think an atom’s second ionization energy would be smaller, the same, or larger than its first ionization energy? Do you think the second ionization energy for an
Postulate a reason why the first ionization energy increases as we progress from left to right across a period.
Atom A has 35 protons and 44 neutrons in its nucleus. Atom B has 35 protons and 46 neutrons in its nucleus. Should we expect similar or different chemical properties for these atoms? Explain.
The first ionization energy is the minimum energy required to remove an electron from a neutral atom. Upon escape from the atom, how would the now free electron differ if you had used more energy
Suppose 12.0 g of silicon (Si) reacts with 70.0 g of oxygen (O2) to give 25.6 g of the compound silicon dioxide (SiO2). In the process, all the silicon gets used up, but some oxygen is left over.(a)
In a mass spectrometer, atoms are ionized and then accelerated through the instrument by a nearby metal plate with a hole in it and an electrical charge on it. Suppose during the ionization process,
An electromagnet bends the path of the fast moving ions in a mass spectrometer so they can reach the detector. The strength of an electromagnets magnetic field depends on the how much voltage is
Two different compounds, both consisting of sodium (Na) and oxygen (O), were analyzed. The data are given below:(a) Fill in the last column of the table.(b) Calculate the %Na and %O for both
Bromine (Br) has two abundant isotopes, one with 44 neutrons and the other with 46 neutrons. Give the full atomic symbols for both isotopes.
The difference between a cation and an anion is (a) A cation has more electrons than an anion.(b) An anion has more electrons than a cation.(c) A cation is negative whereas an anion is positive.(d)
Life on our planet is based on the element carbon, but science fiction writers often like to conjure up silicon-based life-forms. Why have these writers picked on the element Si to create alien life?
Name the three subatomic particles found in an atom and give their relative masses and charges.
How many electrons does a neutral atom of each isotope in Practice Problem 3.8 have?Practice Problem 3.8Bromine (Br) has two abundant isotopes, one with 44 neutrons and the other with 46 neutrons.
Creating a cation from a neutral atom (a) Always takes energy, called the ionization energy.(b) Always requires the removal of an electron from the atom.(c) Never requires the addition of an
Given that the mass of an electron is 5.486 × 10–4 amu, and the mass of a proton is 1.007 amu, calculate how many times heavier a proton is than an electron.
The following is true regarding metals and nonmetals:(a) The majority of elements in the periodic table are metals.(b) Metals like to lose electrons, whereas nonmetals like to gain electrons.(c) Only
In Rutherford’s alpha-particle scattering experiment:(a) How did he interpret the observation that only a very few of the a particles were scattered by the gold foil and most of them went straight
Iron (Fe) and silicon (Si) are common elements in Earth’s crust. How much more massive is iron than silicon?
Suppose all the alpha particles in Rutherford’s experiment went straight through the gold foil with absolutely no deflections. What would this imply about the structure of the atom?
What is the mass in grams of a billion billion (1018) atoms of 24Mg? The atomic mass of 24Mg is 23.9850 amu.
What else besides an atom’s mass number would you need to determine its elemental identity? Explain how you would use it along with the mass number
Chlorine exists as two isotopes in nature, 3517Cl (atomic mass 34.969 amu, abundance 75.77%) and 3717Cl (atomic mass 36.966 amu).(a) What is the percent abundance of the 3717Cl isotope?(b) Calculate
Does knowing how many electrons a neutral atom has tell you its elemental identity? Explain.
Fill in the following table for four neutral atoms: Mass number Atomic number Number of protons Number of neutrons Number of electrons 15 ? ? ? ? ? ? 16 8 ? ? ? ? 37 ? ? ? 17 ? ? ? ? 12 11
How many groups constitute the representative (main-group) elements?
Physicists are fond of saying that an atom is mostly empty space. What justifies this statement?
What do the elements in a group of the periodic table have in common with one another?
Uranium exists mainly as two isotopes in nature, possessing mass numbers 235 and 238. Write the full atomic symbols for both isotopes.
What are the period number and group number of the element that has atomic number 15?
Give the full atomic symbol for this atom: 79e- 79p 118n
Consider the symbol 147C.(a) What is wrong with this symbol?(b) Adjust the atomic number so that the symbol is correct.(c) Adjust the symbol letter so that the symbol is correct.
Which elements with atomic numbers greater than 40 can be expected to have chemical properties similar to those of the element bromine (Br)? What is the periodicity of these two elements?
Write the full atomic symbol for the only atom that has its mass number equal to its atomic number.
What would the periodicity be if the transition metals, lanthanides, and actinides were removed from the periodic table?
Suppose you wanted to turn atoms of lead into atoms of gold. What would you have to do to the nucleus of the lead atoms?
The alkali metals all react with water by giving up an electron to it. Based on their relative positions in the periodic table, which do you think would be more reactive with water—lithium or
What is the difference between an atom’s atomic mass and its mass number?
Arrange the atoms I, Zr, Ag, and Rb from smallest to largest first ionization energy. What does this say about metals versus nonmetals?
Why is the atomic mass scale also called the relative atomic mass scale?
Give the full symbol for the atom or ion that has 26 protons and 30 neutrons in its nucleus and 23 electrons outside its nucleus. Also give the number of the group this element is in.
What is so special about the mass number and atomic mass of 126C?
Give the full symbol for the atom or ion that has eight protons and eight neutrons in its nucleus and ten electrons outside its nucleus. Also give the name of the group this element is in.
How much more massive is an “average” oxygen atom than a 126C atom? (Use the periodic table for the atomic mass of oxygen.)
How much more massive is an “average” titanium (Ti) atom than a 126C atom? (Use the periodic table for the atomic mass of titanium.)
Why is the atomic mass of carbon not listed as 12 on the periodic table if the universal standard is that 126C has an atomic mass of exactly 12 amu?
Suppose we wanted to use one of the more massive atoms, like 23592U, as the standard reference for the atomic mass scale.(a) What would be the universally agreed-upon atomic mass of the 23592U
Bromine exists as only two isotopes in nature, 7935Br (atomic mass 78.918 336 amu, % natural abundance = 50.69%) and 8135Br (atomic mass 80.916 289 amu).(a) What is the percent natural abundance for
Naturally occurring hydrogen on Earth has an atomic mass of 1.0079 amu. Suppose you were on another planet and found the atomic mass of hydrogen to be 1.2000 amu. How would you explain this? (The
While an atom’s mass number and its atomic mass are not the same, they are often quite close to one another. Consider the following: Uranium-235 has an atomic mass of 235.043 93 amu and a percent
(a) In what unique way did Mendeleev order the elements to make his discovery?(b) What was his discovery?(c) How does his ordering differ from the modern ordering?
How did Mendeleev’s discovery aid in discovering additional elements?
Define chemical periodicity with respect to chemical properties.
If one considers just the representative elements, how many groups would the periodic table have?
Considering just the representative elements, what percentage of them are metals, nonmetals, and metalloids? How do your results compare to the same percentages derived using the entire periodic
Give the names associated with groups IA (1), IIA (2), VIA (16), VIIA (17), and VIIIA (18).
What element seems poorly placed in group IA (1), the alkali metals? Why?
How does a group differ from a period in the periodic table?
Suppose you added one electron and one proton to an atom somewhere in the middle of a period. Which way would this move you on the periodic table and by how many places?
Magnesium (Mg) reacts with chlorine (Cl2) to form the compound MgCl2.(a) Predict the formulas for the compounds formed when all the other alkaline earth metals react with chlorine.(b) Predict the
State two things that are unique about the noble gases.
Name and give symbols for five of the transition metals.
How many elements are in each transition metal period of the periodic table? How many are in each lanthanide (rare earth)/actinide period?
Which elements are responsible for changing the chemical periodicity in the periodic table from 8 to 18? From 18 to 32?
Metals are excellent conductors of electricity. Nonmetals are poor conductors of electricity and are called insulators. Some elements have the ability to conduct electricity roughly between that of
It always takes energy to remove an electron from a neutral atom. Explain why, and name the minimum amount of energy it takes to do this.
A student claims that the way to convert a neutral atom of Cl into a Cl– anion is to decrease its atomic number by one while leaving the number of electrons unchanged.(a) Will this give the atom a
What would the charge on a ion be if, starting from the neutral atom: (a) You add three electrons.(b) You remove four electrons. (c) You add two neutrons to the nucleus.
Two students are studying using a plastic model of the atom to which they can easily add or remove electrons, protons, and neutrons. They build a model for the neutral 146C atom. Their next job is to
Something is wrong with the following statement. Fix it. “Adding an electron to a +1 cation yields a neutral atom, but adding an electron to a neutral atom yields a cation.”
A student says that it is possible for an atom’s second ionization energy to be zero because all the work was done creating a cation with the first ionization energy. Is this student right or
What is the trend in first ionization energy as you go down a given group in the periodic table? As you go across a period from left to right?
The trend is for first ionization energy to increase from left to right across a period. Describe any exceptions to this overall trend. Use the portion of the plot that is for the third period atoms
Give the full symbol for the +2 alkaline earth cation that is in the fourth period and has a mass number 21 greater than its atomic number. Explain.
Of the atoms Na, Mg, and Al, which should be the most difficult to ionize? Which has the smallest first ionization energy?
Of the atoms Na, Mg, and K, which should be the most difficult to ionize? Which has the smallest first ionization energy?
Sodium, Na, a metal, rapidly reacts with chlorine, Cl2, a nonmetal.(a) What reason is given for this high reactivity in this chapter?(b) In what ways would you expect the reaction between lithium,
In the reaction of lithium, Li, with nitrogen, N2, three lithium atoms react with one nitrogen atom to give the compound Li3N. Atoms of one of these elements lose one electron; atoms of the other
White light from an incandescent light bulb gives a continuous visible spectrum when the light is passed through a prism. What is meant by the word continuous in this context?
A heated gas made up of individual atoms gives off a line spectrum when the emitted light is passed through a prism. How does a line spectrum differ from a continuous spectrum?
A 34.01-g sample of pure hydrogen peroxide produced at a chemical company contains 32.00 g of oxygen. The rest of the mass is due to hydrogen.(a) What is the percent by mass of oxygen and hydrogen in
Tin, Sn, and oxygen can combine to form two different compounds called oxides. Oxide A contains 78.77% by mass tin. Oxide B contains 88.12% by mass tin. What is the percent by mass of oxygen in each
When wood burns, it combines with oxygen from the atmosphere to produce carbon dioxide, water vapor, and ash. What would you have to do to prove that the law of conservation of matter is not
What evidence exists to support the theory that an atom contains a massive nucleus that is very small relative to the size of the whole atom?
When 5 g of compound A reacts with an unlimited amount of compound B, 7 g of compound C is formed. How many grams of compound B must have reacted, and what law allows you to answer the question?
A student claims that isotopes of the same element have the same number of electrons and protons. Is she correct? Justify your answer.
A student claims that isotopes of the same element have the same number of neutrons but different numbers of protons. Is he correct? Justify your answer.
How do you convert a neutral sulfur atom to an anion carrying a charge of 2–?
A student says that the easiest way to convert a neutral sodium atom to a Na+ cation is to add a proton to its nucleus. She reasons that this is so because protons have a 1+ charge. What is wrong
The mass number of a neutral atom is 19, and its atomic number is 9. The atom contains how many protons, electrons, and neutrons?
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